Acid Potassium Chloride Zinc Electroplating Brightener
Brightener The main brightener can produce remarkable brightening and leveling effect. If the content is too high, the coating in the low current density area will become thinner, and the bottom will be exposed after passivation, which will easily lead to increased brittleness of the coating and affect the passivation quality. The content is too low, the coating bright leveling effect is not good. The content in the bath is maintained at 0.8-2ml/L.
Description
There are two kinds of iron impurities in the bath: one is iron bivalent, the other is iron trivalent. The plating solution can still produce normally when the content of ferric iron reaches 10g/L, which may be related to the fact that ferric iron cannot produce electrochemical co-deposition with zinc on the cathode. The bivalent iron in the bath is more sensitive, so that the range of current density is significantly reduced, especially affecting the quality of the coating at the high current density. In the hull cell experiment, it was found that at 0.2g/L iron, nearly 20mm of the high current end appeared scorched and rough area, and at 0.3g/L, almost half of the sample appeared scorched and rough area, while the coating in the low current area was gray. This plating solution for rolling plating, will appear close to the wall of the rolling plating coating serious scorch, this is the common black spot potassium chloride rolling plating, that is, the barrel eye mark.
Generally in production, when the iron content is greater than 5g/L, the coating in the low current density area will appear yellow. The treatment method of this fault is to add 30% hydrogen peroxide in the plating solution, the ratio is 0.5-1ml/L per liter of the plating solution, and then stir fully, adjust the PH value of the plating solution to 6, and then filter the plating solution to remove the iron in the plating solution.

Common failures and processing method
|
Problem Description |
Probable cause |
Solutions |
|
Poor brightness |
Lack of brightener Lack of softener Organic impurity pollution |
Brightener supplement Softener supplement Activated carbon filtration |
|
Poor coverage No coating in hole and concave
|
Lack of brightener Lack of softener Low potassium chloride The bath temperature becomes higher Aluminum impurity pollution |
Brightener supplement Softener supplement Potassium chloride supplement Lowering temperature Treat with zinc powder |
|
The bright range is narrow and the coating is easy to burn
|
The PH value of the bath increases Lack of zinc Lack of boric acid Lack of softener |
Adjust PH value with dilute hydrochloric acid Zinc chloride supplement Boric acid supplement Softener supplement |
|
The coating has white mist
|
Effect of organic impurities Poor cleaning after plating |
Activated carbon filtration Change the cleaning water |
|
The coating blackening after acid dipping |
Iron impurity Copper impurity |
Hydrogen peroxide treatment and filtration Treat with zinc powder |
|
Roller holes appear in the coating
|
Lack of softener Iron impurity Excessive current Lower zinc Over loading of work
|
Softener supplement Hydrogen peroxide treatment and filtration Lower total current Zinc chloride supplement Reduced loading |
The coating has high brightness, low brittleness, turbidity point of the bath can reach more than 80℃, and bright coating can be plated at 65℃. Its comprehensive performance can be completely comparable with similar foreign products, characteristics are as follows:
1. The bath does not contain ammonium, the wastewater is not polluted and easy to treat.
2. The coating is bright, suitable for low chromium passivation.
3. Adaptable to all kinds of basic materials, such as carbon steel, penetrant steel, cast iron, zinc pressure casting parts can be plated with bright zinc layer.
4. Coating brittleness is small, suitable for thicker zinc plating layer.
5. Additive consumption is low, plating solution maintenance is easy, conducive to reducing production costs.
6. The bath foam is low, both barrel and rack plating can be used.
7. Bath temperature range is wide.
Bath formula and technological parameters
|
|
concentration range |
Standard concentration |
|
KCl |
200-230 g/L |
220g/L |
|
ZnCl |
60-100 g/L |
60g/L (barrel) |
|
Boric Acid |
30-40 g/L |
35 g/L |
|
HL-93 Softening Agent |
20-30 g/L |
25 g/L |
|
HL-93 Brightening Agent |
0.6 ml/L- 1.0 ml/L |
0.8ml/L |
|
Temperature (℃) |
10-55℃ |
40℃ |
|
PH value |
4.8-5.6 |
5.2 |
|
DK (A/dm2) |
0.1-5 |
3 |

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