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Acid Potassium Chloride Zinc Electroplating Brightener

Brightener The main brightener can produce remarkable brightening and leveling effect. If the content is too high, the coating in the low current density area will become thinner, and the bottom will be exposed after passivation, which will easily lead to increased brittleness of the coating and affect the passivation quality. The content is too low, the coating bright leveling effect is not good. The content in the bath is maintained at 0.8-2ml/L.

Description

There are two kinds of iron impurities in the bath: one is iron bivalent, the other is iron trivalent. The plating solution can still produce normally when the content of ferric iron reaches 10g/L, which may be related to the fact that ferric iron cannot produce electrochemical co-deposition with zinc on the cathode. The bivalent iron in the bath is more sensitive, so that the range of current density is significantly reduced, especially affecting the quality of the coating at the high current density. In the hull cell experiment, it was found that at 0.2g/L iron, nearly 20mm of the high current end appeared scorched and rough area, and at 0.3g/L, almost half of the sample appeared scorched and rough area, while the coating in the low current area was gray. This plating solution for rolling plating, will appear close to the wall of the rolling plating coating serious scorch, this is the common black spot potassium chloride rolling plating, that is, the barrel eye mark.

Generally in production, when the iron content is greater than 5g/L, the coating in the low current density area will appear yellow. The treatment method of this fault is to add 30% hydrogen peroxide in the plating solution, the ratio is 0.5-1ml/L per liter of the plating solution, and then stir fully, adjust the PH value of the plating solution to 6, and then filter the plating solution to remove the iron in the plating solution.

20231007111934

Common failures and processing method

Problem Description

Probable cause

Solutions

 

 

 

Poor brightness

Lack of brightener

Lack of softener

Organic

impurity pollution

Brightener supplement

Softener supplement

Activated

carbon filtration

 

Poor coverage

No coating in hole and concave

 

Lack of brightener

Lack of softener

Low potassium chloride

The bath temperature

becomes higher

Aluminum

impurity pollution

Brightener supplement

Softener supplement

Potassium

chloride supplement

Lowering temperature

Treat with zinc powder

 

The bright range is narrow and the coating is easy to burn

 

The PH value of the bath increases

Lack of zinc

Lack of boric acid

Lack of softener

Adjust PH value with dilute hydrochloric acid

Zinc

chloride supplement

Boric acid supplement

Softener supplement

 

The coating has white mist

 

Effect of

organic impurities

Poor cleaning after plating

Activated

carbon filtration

Change the

cleaning water

 

The coating blackening after acid dipping

Iron impurity

Copper impurity

Hydrogen peroxide treatment and filtration

Treat with zinc powder

 

Roller holes appear

in the coating

 

Lack of softener

Iron impurity

Excessive current

Lower zinc

Over loading of work

 

Softener supplement

Hydrogen peroxide treatment and filtration

Lower total current

Zinc

chloride supplement

Reduced loading

 

 

 

The coating has high brightness, low brittleness, turbidity point of the bath can reach more than 80℃, and bright coating can be plated at 65℃. Its comprehensive performance can be completely comparable with similar foreign products, characteristics are as follows:

1. The bath does not contain ammonium, the wastewater is not polluted and easy to treat.

2. The coating is bright, suitable for low chromium passivation.

3. Adaptable to all kinds of basic materials, such as carbon steel, penetrant steel, cast iron, zinc pressure casting parts can be plated with bright zinc layer.

4. Coating brittleness is small, suitable for thicker zinc plating layer.

5. Additive consumption is low, plating solution maintenance is easy, conducive to reducing production costs.

6. The bath foam is low, both barrel and rack plating can be used.

7. Bath temperature range is wide.

 

Bath formula and technological parameters

 

 

concentration range

Standard concentration

KCl

200-230 g/L

220g/L

ZnCl

60-100 g/L

60g/L (barrel)

Boric Acid

30-40 g/L

35 g/L

HL-93 Softening Agent

20-30 g/L

25 g/L

HL-93 Brightening Agent

0.6 ml/L- 1.0 ml/L

0.8ml/L

Temperature (℃)

10-55℃

40℃

PH value

4.8-5.6

5.2

DK (A/dm2)

0.1-5

3

 

20230722160547-018

Hot Tags: acid potassium chloride zinc electroplating brightener, China acid potassium chloride zinc electroplating brightener manufacturers, suppliers, factory

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